Robust cyclometallated Ir(III) catalysts for the homogeneous hydrogenation of N-heterocycles under mild conditions.
نویسندگان
چکیده
Cyclometallated Cp*Ir(N^C)Cl complexes derived from N-aryl ketimines are highly active catalysts for the reduction of N-heterocycles under ambient conditions and 1 atm H2 pressure. The reaction tolerates a broad range of other potentially reducible functionalities and does not require the use of specialised equipment, additives or purified solvent.
منابع مشابه
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ورودعنوان ژورنال:
- Chemical communications
دوره 49 63 شماره
صفحات -
تاریخ انتشار 2013